Health & Safety

 

Grit and Salt Supply - Health & Safety

Rock Salt

1. PRODUCT DESCRIPTION

Rock Salt is approximately 94% pure salt and has a characteristic reddish-brown colour owing to the presence of marl 
(an insoluble material) which is the chief impurity.

Alternative Names: Sodium Chloride, Common Salt, Halite

CAS Number: 007647 14 5

EINECS Number: 231 598 3

Hazardous Ingredient(s): Contains no Hazardous Ingredients
EC Directive 93/112/EEC

2. HAZARDS IDENTIFICATION

Unlikely to cause harmful effects under normal conditions of handling and use.

3. FIRST AID MEASURES

  • Inhalation: Remove patient from exposure.
  • Skin Contact: Wash skin with water
  • Eye Contact: Irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. If symptoms develop, obtain medical attention.
  • Ingestion: Wash out mouth with water and give 200-300ml (half a pint) of water to drink. Obtain medical attention if ill-effects occur.
  • Further Medical Treatment: Symptomatic treatment and supportive therapy as indicated

4. FIRE FIGHTING MEASURES

  • Non-combustible
  • Extinguishing Media: As appropriate for surrounding fire.
  • Fire Fighting Protective No special requirements.
  • Equipment

5. ACCIDENTAL RELEASE MEASURES

  • Clear up spillages.
  • Transfer to a container for disposal.
  • Wash the spillage area with water.
  • Spillages or uncontrolled discharges into watercourses, drains or sewers must be
    IMMEDIATELEY alerted to the Environment Agency or other appropriate regulatory body.

6. HANDLING AND STORAGE

  • Handling: Avoid contact with eyes. Avoid prolonged skin contact.
    Atmospheric levels should be controlled in compliance with
    the occupational exposure limit. Keep away from strong acids
    and common metals. Static electricity can be generated by
    pneumatic conveying, therefore pipes should be bonded and
    earthed, especially where a spark could prove hazardous.

     
  • Storage: Keep away from concentrated acids. Rock Salt can be stored
    outside. Care should be taken to avoid excessive run-off into
    water or onto vegetation.

8. PERSONAL PROTECTION AND EXPOSURE CONTROLS

Wear suitable protective clothing, gloves and eye/face protection. An approved dust mask
should be worn if exposure to levels above the occupational exposure limit is likely.

- Occupational Exposure Standard

- LTEL 8 hr Time Weighted Average
- ppm mg/m³ ppm
- Dust (Total Inhalable Dust) - 10
- Dust (Respirable Dust) - 5

(UK HSE Guidance Note EH40)

9. PHYSICAL AND CHEMICAL PROPERTIES

  • Form: Crystalline solid
  • Colour: Red-brown
  • Odour: Odourless
  • Boiling Point (Deg C): 1413
  • Melting Point (Deg C): 802
  • Density of Sodium Chloride (g/ml) up to 2.165 at 20 Deg C
  • Bulk Density (g/ml) 1.2 to 1.5 approx
  • Solubility (Water) freely soluble
  • Nominal Particle Range Size
  • 10mm Ground Rock Salt 0-10mm
  • 6mmGround Rock Salt 0-6mm

10. STABILITY AND REACTIVITY

  • Hazardous Reactions: Reactions with concentrated acid will produce hydrogen
    chloride. Under wet conditions, will corrode many common
    metals, particularly iron, aluminium and zinc.
     

11. TOXICOLOGICAL INFORMATION

  • Inhalation: High concentrations of dust may be irritant to the respiratory
    tract.
  • Skin Contact: Will remove the natural greases resulting in dryness, cracking
    and possibly dermatitis. Repeated and/or prolonged skincontact
    may cause irritation.
  • Eye Contact: Dust may cause irritation.
  • Ingestion: May cause vomiting and diarrhoea. The swallowing of small
    amounts is unlikely to cause any adverse effects.
  • Long Term Exposure: Repeated ingestion of excessive amounts may cause
    disturbance of body electrolyte and fluid balance.

12. ECOLOGICAL INFORMATION

  • Environmental Fate and Distribution:
  • High Tonnage material with wide disperse use. Solid with low
    volatility. The product is soluble in water. The product has no
    potential for bioaccumulation. The product is predicted to
    have high mobility in soil.
  • Toxicity Low toxicity to aquatic organisms.
  • Effect on Effluent Treatment Adverse effects would not be expected.

13. DISPOSAL CONSIDERATIONS

  • Disposal should be in accordance with local, state or national legislation.

14. TRANSPORT INFORMATION

  • Not classified as Dangerous for Transport.

15. REGULATORY INFORMATION

  • Not classified as Dangerous for Supply / Use

16. OTHER INFORMATION

  • USES: HIGHWAYS DE-ICING
     

This data sheet was prepared in accordance with Directive 93/112/EC and the Chemicals
(Hazard Information and Packaging for Supply) Regulations 1994.
Information in this publication is believed to be accurate and is given in good faith but the
Customer should ensure the suitability for any particular purpose. Accordingly, Darlingtons
Group plc gives no warranty as to the fitness of the Product for use and any implied warranty
or condition (statutory or otherwise) is excluded except to the extent that such exclusion is
prevented by law.

June 1997

 Magic Ice Melt Liquid

P R O D U C T    S A F E T Y    D A T A    S H E E T
 
Page 1/3
1. PRODUCT IDENTIFICATION:
Product Name:                                     Magic Ice Melt Liquid
 
2. PRODUCT COMPOSITION / INFORMATION ON INGREDIENTS:
Potassium Formate                                25% - 45%                                CAS NO: 590-29-4 EINECS NO: 209-677-9
Carbamide                                5% – 25%                                CAS NO:57-13-6 EINECS NO: 200-315-5
 
             
3. HAZARD IDENTIFICATION:
 
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
See section 11 for more detailed information on health effects and symptoms.
 
4. FIRST AID MEASURES:

Skin Contact:                                Immediately wash with soap and water and rinse thoroughly.
Eye Contact:                                Irrigate with copious amounts of water seek medical attention if necessary. 
Ingestion:                                Do not induce vomiting, Seek immediate medical advice
Inhalation:                                Supply fresh air. If required, provide artificial respiration
 
 
5. FIRE FIGHTING MEASURES:
 
Product is not combustible and does not support burning.
May give off Carbon Monoxide and Carbon Dioxides under extreme heat.
In the event of fire, all extinguisher types can be used - select on the basis of other materials present.
 
 
 
6. ACCIDENTAL RELEASE:

(a)     Personal Precautions:          See section 8

(b)          Environmental Precautions:          Contain spills with dikes of soil or non flammable absorbent to minimise 
                    contaminated area. Do not allow material to be released to the environment.
 
 
 
7. HANDLING AND STORAGE:
HANDLING
Ensure good ventilation in the workplace. Keep containers closed when not in use.
STORAGE
                            Store in cool conditions on impermeable floors, out of direct sunlight.    
 
 
 
 
 
PRODUCT NAME:   Magic Ice Melt Liquid
                                                                                                                                                                                                                Page 2/3
8. EXPOSURE CONTROLS / PERSONAL PROTECTION:
EH 40 2005: None listed
Respiratory:                                Use in well ventilated areas
Hands:                                Impervious Gloves.
Eyes:                                Close fitting goggles or face shield (applicable to bulk supply).
Skin:                                Wear personal protective equipment - Apron/Boots/Overalls/weather proof
                                                                                                                           jacket
General Precautions:                The usual precautionary measures for handling chemicals. Use in well ventilated areas. Remain upwind when applying. Keep away from food stuff, beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before and after use
 
 
9. PHYSICAL & CHEMICAL PROPERTIES:

Appearance:                                Clear liquid
Odour:                                none
pH 1:10 at 20°C:                                7.5-9.0
Boiling Range:                                135-153 C
Melting Point:                                Not applicable
Flash Point:                                >93 C closed cup
Flammability / Auto Flammability:                                N/A
Vapour Pressure:                                ~41 to ~10 mm Hg
Relative Density (20°C):                                1.48 to 1.58 g/cm3
Solubility:                                N/A
Partition coefficient:                                N/A
 
 
10. STABILITY & REACTIVITY:

Stability:                                               Stable under normal conditions.
Materials to be avoided:                                                 Sulphuric acid, Hydrochloric acid, hypochlorite and other strong                                                                                         inorganic acids
Dangerous products of decomposition:                                Thermal decomposition products may include oxides of carbon.
 
 
 
11. TOXICOLOGICAL INFORMATION:
 
Acute toxicity: Potassium Formate                           Acute toxicity: Carbamide
 Oral : LD 50 5,500 mg/kg (mus)                               Mouse LD50 = 11,500 mg/kg
                               
                                Skin; Prolonged contact may cause irritation


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